Use of Nut Coke in a blast furnace


Use of Nut Coke in a blast furnace

Metallurgical coke is produced during the carbonization of coking coal blend in a coke oven battery. This coke is produced normally in three size fractions namely coke breeze (size – 10 mm), nut coke (size +10 mm to – 25 mm) and blast furnace (BF) coke (+ 25 mm to – 80 mm).  BF coke is one of the most important factors which affect the economic efficiency of a blast furnace. It also constitutes a great portion of the production costs of the hot metal. The use of nut coke in blast furnace is the essential factor to reduce the costs of iron making. The consumption of the BF coke is strongly related to the CO2 emissions.

History

Earlier there was no use of nut coke in an integrated steel plant and it was sold to other users. Prof. V. I. Loginov suggested in 1960s to charge nut coke into the blast furnace in mixture with sinter.  Though this idea was successfully tested, yet there was initial resistance to use nut coke in blast furnace. In mid 90s Visakhapatnam Steel Plant started using nut coke in their blast furnaces and soon achieved a monthly specific consumption level of over 50 Kg/tHM. The blast furnace of Neelachal Ispat Nigam Limited which was commissioned in February 2002 achieved by 2004-05 a monthly average specific consumption level of over 100 Kg/tHM. Presently the use of nut coke in blast furnace as a substitute of a part of BF coke is considered as a proven technology and nut coke is being used extensively in blast furnaces all over the world. Modern blast furnaces use nut coke in different amount (10-140 Kg/tHM) and in different size of nut coke (10-40 mm).

Nut coke charging with ore burden

Operation of many blast furnaces has demonstrated the possibility of coke saving and increase in productivity when using nut coke mixed with the burden, but the reasons for this phenomenon, and consequently the limit for nut coke consumption, are still not very clear. It was supposed that the decrease in coke consumption while using nut coke is caused by the higher reactivity of nut coke compared with the BF coke and that the nut coke reacts preferably with carbon dioxide and in this way ‘protects’ the charged BF coke from the solution loss reaction in the shaft. However investigations both in the laboratory under simulating solution loss reaction conditions and in industrial blast furnace using nut coke in the ore burden by adding ZrO2 tracer to the coal blend have not proved this theory. The nut coke is used in blast furnace charged along with iron burden as shown in Fig.1.

nut coke in ore burden

Fig 1 BF charge without nut coke (left) and with nut coke (right)

The charging of nut coke in blast furnace is associated with reduction in coke rate and increase in the BF productivity. The replacement ratio of nut coke with BF coke is 1 i.e. nut coke replaces BF coke by equal amounts. The reasons for this replacement are described below.

  • Feeding nut coke mixed with iron bearing materials into blast furnace results into improvement of gas permeability in ‘dry zone’ of the blast furnace. Calculations of gas permeability when mixing nut coke in the sinter layer showed that mixing of 10 volume % of nut coke in the sinter layer resulted in a decrease in the pressure drop in the dry shaft by 5.33 %. With the drop in pressure the gas flow rate increases. This in turn means increased blast volume and increased blast furnace productivity. BF productivity increases by 1.5 % to 2.5 % when using 10 to 20 weight percent of nut coke to BF coke rate.
  • Improvement in the reduction conditions of the iron burden. Due to the nut coke charging along with the ore burden, direct reduction is promoted in the cohesive zone and inhibited in the hearth zone. This also improves the hearth heating.
  • The isothermal reduction in absence of nut coke in the ore burden shows retardation at the elevated temperature due to the formation of liquid slag which blocks the pores of the sinter pieces and inhibits further diffusion of the reducing gas. Mixing nut coke in the sinter burden improves the sinter reducibility through improvement in the gas permeability.
  • Protection of BF coke from the solution loss reaction in the shaft due to higher reactivity of the nut coke

The comparison of a blast furnace operation without and with nut coke is shown in Fig.2

BF with nut coke charge

Fig 2 Blast furnace operation without (left) and with (right) nut coke

Advantages of nut coke usage in blast furnace

  1. Effective utilization of low value product generated during carbonization of coking coal.
  2. Reduces BF coke consumption at the blast furnace.
  3. Improves blast furnace productivity
  4. Reduces production cost of hot metal.
  5. Use of nut coke in the blast furnace reduces overall emissions of CO2 of the steel plant