Alloy Cast Irons

Alloy Cast Irons Alloy cast irons are the casting alloys which are based on the iron (Fe) – carbon (C) – silicon (Si) system. They contain one or more alloying elements intentionally added to improve one or more properties. The addition to the ladle of small amounts of substances such as ferrosilicon (Fe-Si), cerium (Ce), or magnesium (Mg)) that are used to control the size, shape, and/or distribution of graphite particles is termed as inoculation. The quantities of material used for inoculation neither change the basic composition of the solidified cast iron nor alter the properties of individual constituents. Alloying elements, including Si when it exceeds about 3 %, are usually added to increase the strength, hardness, hardenability, or corrosion resistance of the basic iron and are often added in quantities sufficient to affect the occurrence, properties, or distribution of constituents in the microstructure. In gray and ductile cast irons, small amounts of alloying elements such as chromium (Cr), molybdenum (Mo), or nickel (Ni) are added primarily to achieve high strength or to ensure the attainment of a specified minimum strength in heavy sections. Otherwise, alloying elements are used almost exclusively to enhance resistance to abrasive wear or chemical corrosion or to extend service life at elevated temperatures. Classification of alloy cast irons Alloy cast irons can be classified as (i) white cast irons, (ii) corrosion resistant cast irons, and (iii) heat resistant cast irons (Fig 1). Fig 1 Classification of alloy cast irons White cast irons White cast irons are so named because of their characteristically white fracture surfaces. They do not have any graphite in their microstructures. Instead, the C is present in the form of carbides, mainly of the types Fe3C and Cr7C3. Frequently, complex carbides such as (Fe,Cr)3C and (Cr,Fe)7C3,...