Coking Pressure Phenomena and its Influencing Factors Dec17

Coking Pressure Phenomena and its Influencing Factors...

Coking Pressure Phenomena and its Influencing Factors Coking pressure is a phenomenon which has become important because of the use of the double-heated wall, vertical, slot-type coke ovens. In the round beehive ovens as well in the heat recovery coke ovens, which are also being used for coke production, the coal can freely expand upwards and thus the swelling of the charge is accommodated by this free expansion. On the other hand, in the slot-type coke ovens, the expansion of the coal horizontally to the heated wall is restricted. There are several cases of premature failure of oven walls during the coal carbonization process. The erection of the new, larger and taller coke ovens has been accompanied by undesirable occurrences of distorted walls due to the coking pressure resulting in several studies regarding the expansion behaviour of coal during carbonization. The efforts have been focused on developing a reliable test so that coal blends can be tested for safety prior to their use in the coke ovens. Development of coking pressure During carbonization process, coal passes through the plastic stage and volatile matter (VM) evolves during and, to a lesser extent, after that stage. It is normally accepted that coking pressure arises in the plastic stage. In a coke oven chamber, two vertical plastic layers parallel to the heating walls are formed from the beginning of carbonization. As the carbonization proceeds these layers move towards the centre of the oven. At the same time, similar horizontal layers are formed at the top and bottom of the charge. These are joined with the two vertical layers and the whole forms a continuous region that surrounds the uncarbonized coal and it is usually referred to as the ‘plastic envelope’. The permeability of the plastic layers is...

Coal Carbonization for Coke Production Dec08

Coal Carbonization for Coke Production...

Coal Carbonization for Coke Production Coal carbonization is the process by which coal is heated and volatile products (liquid and gaseous) are driven off, leaving a solid residue called coke. Carbonization of coal involves heating coal to high temperatures either in the absence of oxygen (O2) or in control quantity of O2. A gaseous by-product referred to as coke oven gas (COG) along with ammonia (NH3), water, and sulphur compounds are also thermally removed from the coal. The coke which remains after this distillation largely consists of carbon (C), in various crystallographic forms, but also contains the thermally modified remains of various minerals which have been in the original coal. These mineral remains, usually referred to as coke ash, do not burn and are left as a residue after the coke is burned. Until recently, the carbonization of coal was considered as ‘destructive distillation’, but with the increased importance of the products of carbonization, this phrase is falling out of use. Now, the coal carbonization is considered to be a physico-chemical process which depends on the coking rate, operating parameters, coal blend properties and the transport of thermal energy. The heating rate of coal influences the strength and the fissuring properties of coke. In order to arrive at a homogeneous quality, the heating of the coal cake in a coke oven is therefore to be uniform over the total length and height of the oven. In addition to this, the plastic layer migration rate influences the level of thermal stress in the re-solidified mass and therefore, the level of fissuring. The coal carbonization process started at the beginning of the 18th century by carbonizing good quality of coking coal in heaps on the ground, which subsequently led to the development of beehive ovens of...

Theory and Practice of Sintering of Iron ore Nov25

Theory and Practice of Sintering of Iron ore...

Theory and Practice of Sintering of Iron ore Sintering of iron ore is a generic term which is used to describe the process whereby a sinter mix (raw mix or green mix) of iron ore fines, fluxes, fuel (coke breeze) and plant return fines (e.g. mill scale, blast furnace dust, and returned sinter fines etc.) are converted into a particular form of agglomerate. It consists of heating the sinter mix with a particle size of less than 10 mm to such a temperature that surface of each grain of the charge mix starts to melt and the formed melt creates liquid bridges between grains, which, after solidification, ensure formation of a solid porous material called sinter having a screened size normally of 5 mm to 30 mm (upper size can go upto 50 mm to suits local requirements), and which can withstand operating pressure and temperature environment inside the blast furnace (BF). The process of sintering is a thermal operation involving melting and assimilation reactions. The first stage of the sintering process is the formation of the melt which involves the reaction between fine iron ore particles and fluxes. The initial melt is generated from adhering fines during heating via reaction between iron ore and fluxes. Then, nucleus particles are partially assimilated or dissolved into the primary melt to form more melt. Before complete melting is achieved, the sintering temperature drops due to the short residence time at the maximum temperature and then the melt solidifies and mineral phases precipitate, resulting in the formation of the bonding phases. During the sintering process, the chemical reactions are taking place at high temperature and the iron ore and fluxes are combined together and form a sinter cake composed of iron ore, silico-ferrites of calcium and aluminum...

Waste Plastics injection in a Blast Furnace Nov14

Waste Plastics injection in a Blast Furnace...

Waste Plastics injection in a Blast Furnace The recycling of waste plastics (WP) by injecting them in a blast furnace (BF) is being practiced in few BFs especially in japan and Europe. The use of plastics in the BF also recovers energy from the WP and so it is sometimes considered as energy recovery. BF based ironmaking processes can utilize WP by any of the following methods. Carbonization with coal to produce coke. Top charging into the BF, although this generates unwanted tar from the decomposition of the plastics in the shaft. Gasifying the plastics outside the BF. The resultant synthesis gas is then injected through the tuyeres. Injection as a solid through the tuyeres in a similar way to pulverized coal (PC). Normally it is done as a co-injection of WP and coal into the BF. The first attempt for the waste plastics injection (WPI) in a BF was made at the Bremen Steel Works in 1994, with commercial injection starting a year later. The first integrated system for injecting plastic wastes was at NKK’s (now JFE Steel) Keihin Works in Japan. Injecting WP into BF has several environmental, operational and economic advantages. These include the following. Reduction in the amount of plastic wastes being landfilled or incinerated. Lower consumption of both coke and PC, thus saving coal resources. However, neither WP nor PC can completely replace coke. The amount of coke replaced in the BF is partly dependent on the quality of the WP. There is energy resource savings. The benefit of saved resources from mixed WPI is around 11 giga calories per ton (Gcal/t). There is decrease in the carbon dioxide (CO2) emissions since the combustion energy of WP is generally at least as high as that of PC normally injected,...

Understanding Blast Furnace Ironmaking with Pulverized Coal Injection Nov04

Understanding Blast Furnace Ironmaking with Pulverized Coal Injection...

Understanding Blast Furnace Ironmaking with Pulverized Coal Injection Injection of pulverized coal in the blast furnace (BF) was initially driven by high oil prices but now the use of pulverized coal injection (PCI) has become a standard practice in the BF operation since it satisfies the requirement of reducing raw material costs, pollution and also satisfies the need to extend the life of ageing coke ovens. The injection of the pulverized coal into the BF results into (i) increase in the productivity of the BF, i.e. the amount of hot metal (HM) produced per day by the BF, (ii) reduce the consumption of the more expensive coking coals by replacing coke with cheaper soft coking or thermal coals, (iii) assist in maintaining furnace stability, (iv) improve the consistency of the quality of the HM and reduce its silicon (Si) content, and (v) reduce greenhouse gas emissions. In addition to these advantages, use of the PCI in the BF has proved to be a powerful tool in the hands of the furnace operator to adjust the thermal condition of the furnace much faster than what is possible by adjusting the burden charge from the top. Pulverized coal has basically two roles in the operation of a BF. It not only provides part of the heat required for reducing the iron ore, but also some of the reducing gases. For understanding the HM production in a BF with the injection of pulverized coal, it is necessary to understand what is happening inside the BF as well as the chemical reactions and the importance of permeability within the furnace and how the raw materials can affect this parameter. The BF is essentially a counter-current moving bed furnace with solids (iron ore, coke and flux), and later molten...

Understanding Pulverized Coal Injection in Blast Furnace Oct21

Understanding Pulverized Coal Injection in Blast Furnace...

Understanding Pulverized Coal Injection in Blast Furnace Pulverized coal injection (PCI) is a well-established technology for hot metal (HM) production in a blast furnace (BF). It is practiced in most of the BFs and all the new BFs are normally built with PCI capability. The composition and properties of the coal used for injection can influence the operation, stability and productivity of the BF, the quality of the HM, and the composition of the BF gas. The coals being used for the PCI are described in the article under link ‘http://ispatguru.com/coal-for-pulverized-coal-injection-in-blast-furnace/’. The critical aspects of PCI systems include coal preparation, its storage and distribution to ensure uniform feed of coal to each tuyere without fluctuations in the coal delivery rate and its combustion through lance design and oxygen (O2) injection. Coal preparation Pulverization of coal is carried out in a single or multiple grinding mills (pulverizers) depending on the requirements. Grinding and distribution of the coal to the injection lances constitute a major operating cost. Coal reclaimed from coal storage is screened for the removal of the foreign material and any large lump of coal is crushed. The coal is then fed into the mill where it is pulverized and dried. Coal of the required size is transported out of the mill by the hot gas stream, collected in a bag filter and conveyed to the storage bins. Grinding and transport are carried out under an inert atmosphere to minimize the risk of ignition of the dry coal particles. The resultant particle size distribution of the pulverized coal affects it handleability in pneumatic transport equipment and, at high injection rates, its combustibility. Pulverizers grind coal to one of the two size fractions namely (i) pulverized coal where around 70 % to 80 % of...