Properties and Uses of Steelmaking Slag...

Properties and Uses of Steelmaking Slag Steelmaking slag is an integral part of the steelmaking process. It is produced during the separation of the liquid steel from impurities in steelmaking furnace and is a non-metallic by-product of steelmaking process. It occurs as a molten liquid melt and is a complex solution of silicates and oxides which solidifies upon cooling. It primarily consists of silicates, alumina silicates, calcium aluminum silicates, iron oxides and crystalline compounds. During steelmaking, slag is produced in the hot metal pretreatment processes (desulphurization, desiliconization, and dephosphorization etc.), in the primary steelmaking processes (basic oxygen furnace, electric arc furnace, and induction furnace), slag formed during the secondary refining processes (this slag is sometimes called ?secondary refining slag? or ?ladle slag?), and slag formed in tundish during continuous casting of steel (also known as tundish slag). The slag generated in the basic oxygen furnace (BOF) and electric arc furnace (EAF) is of basic nature while the slag is of acidic nature in induction furnace because of the use of silica ramming mass as the lining material. Since most of the steel produced in the world is by BOF and EAF processes, hence slag from these processes is discussed in this article. The processing of the steelmaking slag (Fig 1) is normally carried out by (i) solidifying and cooling of the hot liquid slag, (ii) crushing and magnetic separation treatment of the slag to recover the scrap, (iii) crushing and classification of the slag for grain size adjustment to manufacture the slag product, and (iv) aging treatment of the slag product for improving its quality and volumetric stability. These processes are explained below.   Fig 1 Processing of steelmaking slag As steelmaking slag is formed, it is in a molten or red-hot state at...

Hot Metal

Hot Metal Hot metal (HM) is the output of a blast furnace (BF). It is liquid iron which is produced by the reduction of descending ore burden (iron ore lump, sinter, and pellet) by the ascending reducing gases. HM gets collected in the hearth of the BF. From the hearth, the HM is tapped from the taphole of the BF after an interval of time. Normally in large BFs, HM tapping rates of 7 ton/min and liquid tapping velocities of 5 m/sec, in tap holes of 70 mm diameter and 3.5 m long, are typically encountered. The tapping rate of HM is strongly influenced by the taphole condition and taphole length. Generally the temperature of tapped HM varies in the range of 1420 deg C to 1480 deg C. The tapped HM is handled in the two stages namely (i) handling of the HM in the cast house i.e. from taphole to the hot metal ladles (open top or torpedo), and (ii) transport of HM ladles to the point of HM consumption. Presently most of the HM is consumed within integrated steel plants for steel making. The HM is transferred to the steel melting shop for making of steel. The HM which is not sent for steel making is cast into pig iron in pig casting machine for use in steel making later as cold charge or is sold to foundries or to mini steel plants having induction furnaces as merchant pig iron. HM can also be granulated by a process which is known as ‘Granshot’ process. Presently the Granshot plants for the production of GPI are working at six places namely (i) Uddeholm, Sweden, (ii) SSAB Lulea, Sweden, (iii) Voest Alpine, Donawitz, (iv) Saldanha steel, South Africa, (v) SSAB Oxelosund, Sweden, and (vi)...

Natural gas and its Usage in Iron and Steel Industry...

Natural gas and its Usage in Iron and Steel Industry Natural gas (NG) is an environmentally friendly non-renewable gaseous fossil fuel which is extracted from deposits in the earth. It is a clean and green fuel with a high efficiency and plays a major role in helping many industries cut emissions and improve the overall air quality. It is normally supplied as (i) piped natural gas (PNG), (ii) compressed natural gas (CNG), and (iii) liquefied natural gas (LNG). Natural gas is a mixture of hydro-carbons consisting primarily of methane (CH4), generally in a percentage of over 85 % by volume. Other hydro-carbons in NG include varying amounts of various higher alkanes such as ethane, propane, and butane etc. It also contains water vapour (H2O) at varying degrees of saturation, or condensed water. It may also contain some small percentage of nitrogen (N2), carbon dioxide (CO2) and hydrogen sulphide (H2S) and helium (He) etc. NG burns with a clean blue luminous flame when mixed with the requisite amount of air and ignited. It is considered one of the cleanest burning fuels. On burning, it produces primarily heat, CO2, and water vapour. NG is a fuel found in deposits in its gas phase. It is colourless and odourless, non-toxic, and lighter than air. It does not contain olefins (hydrocarbons produced during the process of destructive distillation or reforming). It is a highly flammable and combustible gas. Its CAS number is 8006-14-2 and UN number is 1971. Quantities of natural gas are measured in normal cubic meters (corresponding to 0 deg C and 1 atmosphere pressure) or standard cubic feet (corresponding to 16 deg C and 14.73 pounds per square inch absolute pressure). The higher heat value of one cubic meter of natural gas varies from around 9500...

Thermal Coal

Thermal Coal Thermal coal is a type of bituminous coal which is used to provide heat energy in combustion in various types of furnaces via the pulverized fuel method because of its high calorific value (CV). It is also sometimes called as non-coking coal, steam coal, or boiler coal. It includes all those bituminous coals which are not included under coking coal category. It is characterized by higher volatile matter (VM) than anthracite (more than 10 %) and lower carbon (C) content (less than 90 % fixed C). Its gross CV is greater than 5700 kcal/kg on an ash?free but moist basis. The greatest use of thermal coal is for the generation of steam in the boilers for the purpose of generation of electricity. Thermal coal is also used in some of the processes for ironmaking especially in the production of direct reduced iron (DRI) and in the smelting reduction processes for the production of hot metal (HM). Thermal coal is a complex heterogeneous substance. Hence, it has no fixed chemical formula. Its characteristics and hence its CV vary widely. Thermal coals like other coals also contain carbon (C), oxygen (O2), and hydrogen (H2). The other constituents in thermal coals include sulphur (S), nitrogen (N2), ash, chlorine (Cl), and sodium (Na). The quality of thermal of coals is based on the amount of C, O2, and H2 present in coal. The metallic elements in the thermal coal contribute to the coal ash. The chemical structure of the organic molecules of the thermal coal is very complex and is dependent on the rank of the coal. It varies from one coal to another coal. Typical structure of thermal coal is given in Fig 1. Fig 1 Typical structure of thermal coal The performance of the...

Coal for Pulverized Coal Injection in Blast Furnace...

Coal for Pulverized Coal Injection in Blast Furnace Injection of pulverized coal in the blast furnace (BF) was initially driven by high oil prices but now the use of pulverized coal injection (PCI) has  become a standard practice in the operation of a BF since it satisfy the requirement of reducing raw material costs, pollution and also satisfy the need to extend the life of ageing coke ovens. The injection of the pulverized coal into the BF results into (i) increase in the productivity of the BF, i.e. the amount of hot metal (HM) produced per day by the BF, (ii) reduce the consumption of the more expensive coking coals by replacing coke with cheaper soft coking or thermal coals, (iii) assist in maintaining furnace stability, (iv) improve the consistency of the quality of the HM and reduce its silicon (Si) content, and (v) reduce greenhouse gas emissions. In addition to these advantages, use of the PCI in the BF has proved to be a powerful tool in the hands of the furnace operator to adjust the thermal condition of the furnace much faster than what is possible by adjusting the burden charge from the top. Schematic diagram of a BF tuyere showing a pulverized coal injection lance is at Fig 1. Fig 1 Schematic diagram of a BF tuyere showing a pulverized coal injection lance Several types of coals are being used for PCI in the BF. In principle, all types of coals can be used for injection in BF, but coking coals are not used for injection since they are costly, have lower availability and are needed for the production of coke. Also, if coking coals are used for injections in BF, They lead to tuyere coking. Hence, coals used for injection...

Metallurgical Coal

Metallurgical Coal Metallurgical coal is also called ‘met coal’ or ‘coking coal. It is a bituminous coal which allows the production of a coke suitable to support a blast furnace (BF) charge. It is distinguished by the strong low-density coke produced when the coal is heated in a low oxygen (O2) environment or in absence of air to reduce mineral impurities (e.g. less sulphur, phosphorus). On heating, the coal softens, and volatile components evaporate and escape through pores in the mass. On cooling, the resultant coke has swollen, becoming a larger volume. The strength and density of coke is particularly important when it is used in a BF, as the coke supports part of the ore and flux burden inside the BF. Metallurgical coal possesses the ability to soften and re-solidify into a coherent, porous mass, when heated from 300 deg C to 550 deg C in the absence of air in a confined space. The conversion from coal to coke occurs in chambers called coke ovens where the volatiles from the coal escape, leaving behind what is referred to as metallurgical coke, which reaches a temperature of around 1,000 deg C to 1200 deg C before being removed from the ovens. The coking cycle is normally dependent on several parameters. Coke is used primarily as a fuel and a reducing agent in a BF. The gross calorific value (CV) of the metallurgical coal is greater than 5700 kcal/kg on an ash?free but moist basis. It presents unique plastic properties during carbonization which in turn produces a porous solid, high in carbon (C) coke. Metallurgical coals, when heated at a moderate rate in the absence of air, undergo complex and continuous changes in chemical composition and physical character. During carbonization, most bituminous coals, except those bordering...